(E)-1-(4-Fluorophenyl)-2-(2-oxidonaphthalen-1-yl)diazen-1-ium

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(E)-1-(3-Formyl­phen­yl)-2-(2-oxidonaphthalen-1-yl)diazen-1-ium

In the title zwitterion, C17H12N2O2, the dihedral angle between the benzene ring and naphthalene ring system is 11.76 (7)° and an intra-molecular N-H⋯O hydrogen bond exists. In the crystal, molecules are linked via pairs of C-H⋯O hydrogen bonds, forming inversion dimers.

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(E)-1-(3-Chloro­phen­yl)-2-(2-oxidonaphthalen-1-yl)diazen-1-ium

The title zwitterion,, C16H11ClN2O, is approximately planar, the dihedral angle between the benzene ring and naphthalene ring system is 1.55 (13)°; an intra-molecular N-H⋯O hydrogen bond stabilizes the planar conformation. In the crystal, π-π stacking between the benzene ring and the naphthalene ring system of adjacent mol-ecules links the mol-ecules into supra-molecular chains running along th...

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1-(4-Hy­droxy­phen­yl)-2-(2-oxidonaphthalen-1-yl)diazen-1-ium methanol hemisolvate

In the title compound, C16H12N2O2·0.5CH3OH, the H atom of the -OH group has been transfered to the N atom in the azo group, forming a zwitterion. Hence, there is an intra-molecular N-H⋯O, rather than an O-H⋯N, hydrogen bond in the mol-ecule. The mol-ecule is almost planar, the dihedral angle between the benzene ring and the mean plane of the naphthalene ring system being 4.51 (6)°. In the cryst...

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1-(4-Cyano­phenyl­diazen-2-ium-1-yl)-2-naphtholate

In the mol-ecule of the zwitterionic title compound, C(17)H(11)N(3)O, the naphthalene ring system is planar [maximum deviation = 0.029 (3) Å] and is oriented at a dihedral angle of 3.55 (3)° with respect to the benzene ring. An intra-molecular N-H⋯O hydrogen bond results in the formation of a planar six-membered ring. In the crystal structure, inter-molecular C-H⋯O inter-actions link the mol-ec...

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4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate

The title compound {systematic name: 4-[bis(4-fluorophenyl)methyl]piperazin-1-ium 2,4,6-tri-nitro-phenolate}, C(17)H(19)F(2)N(2) (+)·C(6)H(2)N(3)O(7) (-), is the picrate salt of a piperazine-supported amine bearing a benzhydryl substituent on one of its N atoms. During co-crystallisation, protonation took place on the N atom of the secondary amine functionality. The non-aromatic six-membered he...

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ژورنال

عنوان ژورنال: IUCrData

سال: 2017

ISSN: 2414-3146

DOI: 10.1107/s2414314617000396